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  1. ABSTRACT

    The globular cluster (GC) systems of low-mass late-type galaxies, such as NGC 2403, have been poorly studied to date. As a low mass galaxy (M*  = 7 × 109 M⊙), cosmological simulations predict NGC 2403 to contain few, if any, accreted GCs. It is also isolated, with a remarkably undisturbed HI disc. Based on candidates from the literature, Sloan Digital Sky Survey and Hyper Suprime-Cam imaging, we selected several GCs for follow-up spectroscopy using the Keck Cosmic Web Imager. From their radial velocities and other properties, we identify eight bona-fide GCs associated with either the inner halo or the disc of this bulgeless galaxy. A stellar population analysis suggests a wide range of GC ages from shortly after the big bang until the present day. We find all of the old GCs to be metal-poor with [Fe/H] ≤ −1. The age–metallicity relation for the observed GCs suggests that they were formed over many Gyr from gas with a low effective yield, similar to that observed in the SMC. Outflows of enriched material may have contributed to the low yield. With a total system of ∼50 GCs expected, our study is the first step in fully mapping the star cluster history of NGC 2403 in both space and time.

     
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  2. Abstract

    Near‐infrared (NIR) fluorescent dyes with favorable photophysical properties are highly useful for bioimaging, but such dyes are still rare. The development of a unique class of NIR dyes via modifying the rhodol scaffold with fused tetrahydroquinoxaline rings is described. These new dyes showed large Stokes shifts (>110 nm). Among them, WR3, WR4, WR5, and WR6 displayed high fluorescence quantum yields and excellent photostability in aqueous solutions. Moreover, their fluorescence properties were tunable by easy modifications on the phenolic hydroxy group. Based on WR6, two NIR fluorescent turn‐on probes, WSP‐NIR and SeSP‐NIR, were devised for the detection of H2S. The probe SeSP‐NIR was applied in visualizing intracellular H2S. These dyes are expected to be useful fluorophore scaffolds in the development of new NIR probes for bioimaging.

     
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  3. Abstract

    Near‐infrared (NIR) fluorescent dyes with favorable photophysical properties are highly useful for bioimaging, but such dyes are still rare. The development of a unique class of NIR dyes via modifying the rhodol scaffold with fused tetrahydroquinoxaline rings is described. These new dyes showed large Stokes shifts (>110 nm). Among them, WR3, WR4, WR5, and WR6 displayed high fluorescence quantum yields and excellent photostability in aqueous solutions. Moreover, their fluorescence properties were tunable by easy modifications on the phenolic hydroxy group. Based on WR6, two NIR fluorescent turn‐on probes, WSP‐NIR and SeSP‐NIR, were devised for the detection of H2S. The probe SeSP‐NIR was applied in visualizing intracellular H2S. These dyes are expected to be useful fluorophore scaffolds in the development of new NIR probes for bioimaging.

     
    more » « less